Copper-catalyzed borylative cyclization of γ,δ-unsaturated aromatic oxime esters to (borylmethyl)pyrrolidines,Organic Chemistry Frontiers

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Copper-catalyzed borylative cyclization of γ,δ-unsaturated aromatic oxime esters to (borylmethyl)pyrrolidines
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-09-17 , DOI: 10.1039/d0qo01064b
Youcan Zhang _{1,

2,

3} , Xiao-Feng Wu _{1,

2,

3,

4,

5}

Affiliation

An efficient copper-catalyzed aminoborylation of γ,δ-unsaturated aromatic oxime esters with bis(pinacolato)diboron has been developed. A variety of α-(borylmethyl)pyrrolidine derivatives were constructed in high yields under mild conditions. Notably, examples of converting the obtained aminoborylated product, including cycloaddition, oxidation, and coupling reactions, have been given as well.

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