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A Novel Copper-Catalyzed Synthesis of N-Monosubstituted 2-Alkynimidamides from 1-Alkynes and Trichloroacetamidines
Letters in Organic Chemistry ( IF 0.7 ) Pub Date : 2020-08-31 , DOI: 10.2174/1570178616666191023142821 Hossein Fasihi Dastjerdi 1 , Manijeh Nematpour 2 , Elham Rezaee 2 , Mehdi Jahani 3 , Sayyed Abbas Tabatabai 2
中文翻译：
1-炔烃和三氯乙am的新型铜催化合成N-单取代2-炔酰胺
更新日期：2020-08-31
Letters in Organic Chemistry ( IF 0.7 ) Pub Date : 2020-08-31 , DOI: 10.2174/1570178616666191023142821 Hossein Fasihi Dastjerdi 1 , Manijeh Nematpour 2 , Elham Rezaee 2 , Mehdi Jahani 3 , Sayyed Abbas Tabatabai 2
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A one-pot Cu-catalyzed synthesis of functionalized alkynyl imidamide by terminal alkynes, trichloroacetonitrile and aniline or benzyl amine is reported. The compounds were produced via coupling reaction of terminal alkynes with trichloroacetamidine. This method was performed under mild, ligand-free conditions and easy work-up method.
中文翻译：
1-炔烃和三氯乙am的新型铜催化合成N-单取代2-炔酰胺
据报道，通过末端炔烃，三氯乙腈和苯胺或苄基胺的一锅铜催化合成功能化炔基亚酰胺。该化合物是通过末端炔与三氯乙am的偶合反应制备的。该方法在温和，无配体的条件下和简便的后处理方法下进行。
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