A novel three-dimensional luminescence Cd-MOF sensor with the molecular formula {[(CH₃)₂NH₂]₂ Cd₃(ptptc)₂} (complex 1) has been synthesized by using terphenyl-3,3′,5,5′-tetracarboxylic acid (H₄ptptc) and Cd(NO₃)₂·4H₂O under solvothermal conditions. Single crystal X-ray diffraction analysis shows that complex 1 crystallizes in the monoclinic system C2/c space group and consists of one-dimensional channels. Complex 1 exhibits characteristic fluorescence emission (λ_em = 380 nm) both in solid state and solvents upon excitation at 300 nm. Real-time fluorescence quenching of complex 1 was observed in the fluorescence sensing of acetone vapor and picric acid. Intriguingly, ppm scale detection limit for acetone vapor in air and nano-mole scale detection limit for picric acid in water were observed. Moreover, good reusability and liner/nonlinear relationships were observed in the fluorescent titration.

利用三联苯-3,3'，5，合成了分子式为{[（CH ₃）₂ NH ₂ ] ₂ Cd ₃（ptptc）₂ }（络合物1）的新型三维Cd-MOF传感器。 5'-四羧酸（H ₄ ptptc）和Cd（NO ₃）₂ ·4H ₂ o在溶剂热条件。X射线单晶衍射分析表明，配合物1在单斜晶系C 2 / c空间群中结晶，由一维通道组成。综合大楼1显示出特征性荧光发射（λ _EM 在300nm处= 380纳米）无论是在激发后固态和溶剂。在丙酮蒸气和苦味酸的荧光检测中观察到了配合物1的实时荧光猝灭。有趣的是，观察到了空气中丙酮蒸气的ppm标度检测限和水中苦味酸的纳摩尔标度检测限。此外，在荧光滴定法中观察到良好的可重复使用性和线性/非线性关系。