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Self-provided microbial electricity enhanced wastewater treatment using carbon felt anode coated with amino-functionalized Fe3O4
Journal of Water Process Engineering ( IF 6.3 ) Pub Date : 2020-09-17 , DOI: 10.1016/j.jwpe.2020.101649
Hongbo Liu , Yi Zhang , Yanhong Zhou , Zhongbing Chen , Eric Lichtfouse

Bioelectricity can be produced from wastewater using microbial fuel cells (MFCs) that produce electricity during electrochemical and biochemical reactions, yet actual applications of wastewater MFCs are limited; a self-provided microbial electricity enhanced wastewater treatment method is proposed producing microbial power and enhanced pollutants removal simultaneously. A carbon felt coated with amino-functionalized Fe3O4 particles was synthesized; power generation, removal of chemical oxygen demand (COD) and NH4+-N were evaluated with cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), cell voltage and treatment efficiency. Results showed that the amino-Fe3O4 coated anode led to higher NH4+-N removal efficiency of 97.7 % than the Fe3O4 coated anode of 48.9 %. Moreover, the maximum power density of the amino-Fe3O4 anode is 208.67 mW/m2, 35.1 % higher than that of the Fe3O4 anode. This finding was explained by the presence of protonated amino groups NH4+ that favored the attachment of negatively charged bacteria. Amino-functionalization of the anode promotes a promising, novel technology to treat wastewater while producing electricity.



中文翻译:

使用氨基官能化的Fe 3 O 4涂层的碳毡阳极,自给自足的微生物电力增强废水处理

可以使用微生物燃料电池(MFCs)从废水中产生生物电,而微生物燃料电池在电化学和生化反应过程中会产生电能,但是废水MFCs的实际应用受到限制。提出了一种自给自足的微生物电强化废水处理方法,可同时产生微生物能和提高污染物去除率。合成了涂覆有氨基官能化的Fe 3 O 4颗粒的碳毡;利用循环伏安法(CV),电化学阻抗谱(EIS),电池电压和处理效率对发电,化学需氧量(COD)和NH 4 + -N的去除进行了评估。结果表明,氨基Fe 3 O 4涂层阳极导致的NH 4 + -N去除效率比Fe 3 O 4涂层阳极的48.9%更高,为97.7 %。此外,氨基-Fe 3 O 4阳极的最大功率密度为208.67mW / m 2,比Fe 3 O 4阳极的最大功率密度高35.1%。质子化的氨基NH 4 +的存在有利于带负电细菌的附着,从而解释了这一发现。阳极的氨基官能化促进了一种有前途的新颖技术,可在发电的同时处理废水。

更新日期:2020-09-17
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