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Visualizing the helical stacking of octahedral metallomesogens with a chiral core.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-09-16 , DOI: 10.1039/d0cc05930g Go Watanabe 1 , Hideyo Watanabe 2 , Kota Suzuki 2 , Hidetaka Yuge 2 , Shintaro Yoshida 1 , Takuyoshi Mandai 1 , Shigetaka Yoneda 1 , Hisako Sato 3 , Mitsuo Hara 4 , Jun Yoshida 2
Chemical Communications ( IF 4.3 ) Pub Date : 2020-09-16 , DOI: 10.1039/d0cc05930g Go Watanabe 1 , Hideyo Watanabe 2 , Kota Suzuki 2 , Hidetaka Yuge 2 , Shintaro Yoshida 1 , Takuyoshi Mandai 1 , Shigetaka Yoneda 1 , Hisako Sato 3 , Mitsuo Hara 4 , Jun Yoshida 2
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A combination of grazing-incidence X-ray diffraction and molecular dynamics simulation studies led to the visualization of the stacking structure of a helical columnar liquid crystal formed by enantiopure octahedral metallomesogens with ΔΛ chirality. The helical structure was elucidated as a hybrid of two major proposed structures.
中文翻译：
可视化具有手性核的八面体金属成因分子的螺旋堆积。
掠入射X射线衍射和分子动力学模拟研究相结合，导致了由具有手性ΔΛ的对映纯八面体金属成因剂形成的螺旋柱状液晶的堆叠结构的可视化。螺旋结构被阐明为两种主要提议结构的混合体。
更新日期：2020-10-13
中文翻译：
可视化具有手性核的八面体金属成因分子的螺旋堆积。
掠入射X射线衍射和分子动力学模拟研究相结合，导致了由具有手性ΔΛ的对映纯八面体金属成因剂形成的螺旋柱状液晶的堆叠结构的可视化。螺旋结构被阐明为两种主要提议结构的混合体。
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