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Customized Chiral Colloids
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2020-09-15 , DOI: 10.1021/jacs.0c07315
Mingzhu Liu 1 , Fangyuan Dong 1 , Nicolle S Jackson 1 , Michael D Ward 1 , Marcus Weck 1
Affiliation  

This contribution describes a synthetic strategy for the fabrication of multicomponent colloidal "molecules" with controllable complex morphologies and compositionally distinct lobes. Using 3-(trimethoxysilyl)propyl methacrylate (TPM) as the building block, the methodology enables a scalable bulk synthesis of customized chiral colloidal particles with geometric and compositional chirality by a sequential seeded growth method. The synthetic protocol presents a versatile platform for constructing colloidal molecules with multiple components having customized shapes and functionalities, with the potential to impact the design of chromatic patchy particles, colloidal swimmers, and chiral optical materials, as well as informing programmable assembly.

中文翻译:

定制手性胶体

这一贡献描述了一种合成策略,用于制造具有可控复杂形态和成分不同的叶状体的多组分胶体“分子”。该方法使用甲基丙烯酸 3-(三甲氧基甲硅烷基)丙酯 (TPM) 作为构建模块,通过顺序种子生长方法可大规模合成具有几何和组成手性的定制手性胶体颗粒。该合成协议提供了一个多功能平台,用于构建具有自定义形状和功能的多个组件的胶体分子,有可能影响彩色斑块粒子、胶体游泳者和手性光学材料的设计,以及通知可编程组装。
更新日期:2020-09-15
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