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Photodissociation Dynamics of CF2I2 in CCl4 Solution Probed by Femtosecond Infrared Spectroscopy
Bulletin of the Korean Chemical Society ( IF 1.7 ) Pub Date : 2020-09-16 , DOI: 10.1002/bkcs.12096
Seongchul Park 1 , Juhyang Shin 1 , Hojeong Yoon 1 , Manho Lim 1
Affiliation  

Dynamics of photodissociation of CF2I2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I2 molecule producing CF2, which bimolecularly reacts to produce C2F4.
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中文翻译:

飞秒红外光谱法探测CCl4溶液中CF2I2的光解离动力学

在350 nm激发后溶液中CF 2 I 2的光解离动力学。一个I原子立即解离,所有解离的I重新结合形成反应物或异构体,这些反应物或异构体迅速释放I 2分子,生成CF 2,双分子反应生成C 2 F 4
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更新日期:2020-10-19
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