An intermolecular phenolic coupling promoted by iodosobenzene leading to Pummerer’s ketone and its analogs has been developed. The reaction allows for the preparation of products derived from both phenols and naphthols, bearing various substitution patterns, in excellent diasteroselectivity. The Pummerer’s ketone-type compounds form as sole low molecular weight products, which together with simple experimental conditions, makes the reaction a convenient entry to this important molecular motif.

中文翻译：

---

碘代苯促进的氧化酚偶联反应合成Pummerer's酮及其类似物

已经开发了由碘代苯促进的分子间酚偶联，导致了Pummerer的酮及其类似物。该反应允许以优异的非对映选择性制备具有多种取代模式的衍生自酚和萘酚的产物。Pummerer的酮类化合物是唯一的低分子量产物，与简单的实验条件一起使该反应成为进入该重要分子基序的便捷途径。