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Recent advances in one-pot functionalization of graphene using electrochemical exfoliation of graphite: A review study
Synthetic Metals ( IF 4.0 ) Pub Date : 2020-11-01 , DOI: 10.1016/j.synthmet.2020.116549
Hamed Aghamohammadi , Reza Eslami-Farsani , Mahdi Torabian , Nima Amousa

Abstract Electrochemical exfoliation of graphite is a simple, cost-effective, and environment-friendly method for the large-scale production of high-quality graphene. Recently, the production of the functionalized graphene using the electrochemical exfoliation of graphene has attracted great attention. Also, the synthesis of graphene /nanoparticles is a new research topic for researches owing to their unique properties. To date, extensive works have been performed for the functionalization of graphene. However, the proposed methods are mainly expensive and time-consuming. So, the development of a simple method for the large-scale production of functionalized graphene is necessary. Reviewing the recent studies indicates that the graphene/ nanoparticle composites can be synthesized using the one-step electrochemical exfoliation of graphite. Therefore, in this study, it is tried to review the recent papers on the one-step electrochemical method for the exfoliation and functionalization of graphite. Different approaches have been employed for the in-situ exfoliation and functionalization by the electrochemical route. In this review study, the details of electrochemical processes (such as type of graphite, electrolyte, voltage, etc.), preparation of electrodes, and proposed mechanisms for one-step exfoliation and functionalization of graphite are reviewed.

中文翻译:

石墨烯电化学剥离法一锅法石墨烯功能化的最新进展:综述研究

摘要 石墨的电化学剥离是一种简单、经济、环保的大规模生产高质量石墨烯的方法。最近,利用石墨烯的电化学剥离生产功能化石墨烯引起了人们的极大关注。此外,石墨烯/纳米颗粒的合成由于其独特的性质而成为研究的新课题。迄今为止,已经为石墨烯的功能化进行了大量工作。然而,所提出的方法主要是昂贵且耗时的。因此,有必要开发一种用于大规模生产功能化石墨烯的简单方法。回顾最近的研究表明,石墨烯/纳米颗粒复合材料可以使用石墨的一步电化学剥离来合成。因此,在本研究中,试图回顾最近关于石墨剥离和功能化一步电化学方法的论文。已经采用不同的方法通过电化学途径进行原位剥离和功能化。在这项综述研究中,综述了电化学过程的细节(如石墨的类型、电解质、电压等)、电极的制备以及石墨一步剥离和功能化的拟议机制。
更新日期:2020-11-01
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