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Effect of Co2+ and Ni2+ co-doping on SnO2 synthesized via phytogenic method for photoantioxidant studies and photoconversion of 4-nitrophenol
Materials Today Communications ( IF 3.7 ) Pub Date : 2020-09-16 , DOI: 10.1016/j.mtcomm.2020.101677
Shaidatul Najihah Matussin , Mohammad Hilni Harunsani , Ai Ling Tan , Moo Hwan Cho , Mohammad Mansoob Khan

Tin dioxide (SnO2) and cobalt and nickel co-doped-SnO2 (Co,Ni)-SnO2 nanoparticles (NPs) have been synthesized via aqueous leaf extract of Tradescantia spathacea, which is a phytogenic and green method. The structural, optical and surface morphological studies were analyzed using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV-Vis diffuse reflectance spectrophotometer (UV-Vis DRS), Photoluminescence spectroscopy (PL), Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and BET. Powder XRD data revealed tetragonal rutile structure of SnO2 in which the crystallite size was in the range of 13 to 22 nm. The attachment of organic compounds on the surface of NPs was confirmed by FTIR. UV-Vis DRS showed the red-shift to visible light in which the reduction of band gap was confirmed by Valence band X-ray photoelectron spectroscopy (VB-XPS). The PL intensity was reduced indicating the successful incorporation of Co and Ni dopants into SnO2 lattice. The photoantioxidant activities of the SnO2 and (Co,Ni)-SnO2 NPs were enhanced under visible light. Similarly, the photocatalytic conversion of 4-nitrophenol to 4-nitrophenolate ions was also enhanced under the visible light irradiation.



中文翻译:

Co 2+和Ni 2+共掺杂对用植物性方法合成的SnO 2的光抗氧化剂研究和4-硝基苯酚的光转化的影响

紫茎泽兰的叶片提取物是一种植物性绿色方法合成了二氧化锡(SnO 2)和钴镍共掺杂的SnO 2(Co,Ni)-SnO 2纳米颗粒(NPs)。使用粉末X射线衍射(XRD),傅立叶变换红外光谱(FTIR),紫外-可见漫反射光谱仪(UV-Vis DRS),光致发光光谱(PL),扫描电子显微镜对结构,光学和表面形态学进行了分析(SEM),X射线光电子能谱(XPS)和BET。粉末XRD数据显示SnO 2的四方金红石结构其中微晶尺寸在13至22nm的范围内。FTIR证实了有机化合物在NPs表面的附着。UV-Vis DRS显示出向可见光的红移,其中通过价带X射线光电子能谱(VB-XPS)证实了带隙的减小。PL强度降低,表明成功地将Co和Ni掺杂剂掺入SnO 2晶格中。SnO 2和(Co,Ni)-SnO 2 NP的光抗氧化活性在可见光下得到增强。同样,在可见光照射下,4-硝基苯酚向4-硝基苯酚盐离子的光催化转化也得到增强。

更新日期:2020-09-16
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