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Engineering of Zirconium based metal-organic frameworks (Zr-MOFs) as efficient adsorbents
Materials Science and Engineering: B ( IF 3.9 ) Pub Date : 2020-09-16 , DOI: 10.1016/j.mseb.2020.114766
Khalil Ahmad , Muhammad Altaf Nazir , Ahmad Kaleem Qureshi , Ejaz Hussain , Tayyaba Najam , Muhammad Sufyan Javed , Syed Shoaib Ahmad Shah , Muhammad Khurram Tufail , Shahid Hussain , Naseem Ahmad Khan , Habib-ur-Rehman Shah , Muhammad Ashfaq

Synthesis of porous materials is very attractive due to their various applications in era of water purification. The other advantage is due the structural and functionality of stable MOFs-based porous materials. Metal-organic frameworks (MOFs) are spongy like structures that are composed of transition metals coordinately linked or protected via ligands may be responsible for the active centers and large surface area. In this mini review, we have emphasized the development of water stable Zr-MOFs that have been potentially used as emerging adsorbents for cationic and anionic contaminants in water. The main focus of this review is on the detail study of stability as well as the factors affecting the stability of Zr-based MOFs, including the adsorbent capacities, thermodynamics and kinetic studies. Moreover we have discussed the introduction of metal ions to organic linkers having more replaceable atoms that makes them more reliable adsorbents than other conventional adsorbents. Of note the Zr-MOFs exhibit as an emerging platform for the cost effective, eco-friendly approach and interesting adsorbent-adsorbate interactions for water treatment.



中文翻译:

锆基金属有机骨架(Zr-MOF)作为有效吸附剂的工程设计

多孔材料的合成由于在水净化时代的各种应用而非常有吸引力。另一个优点是由于稳定的基于MOF的多孔材料的结构和功能。金属有机骨架(MOF)是海绵状结构,由过渡金属组成,这些过渡金属通过配体配位连接或受保护,可能是活性中心和大表面积的原因。在本篇简短的综述中,我们强调了水稳定的Zr-MOF的开发,这些Zr-MOF可能被用作水中阳离子和阴离子污染物的新兴吸附剂。本文的重点是对稳定性以及影响Zr基MOF稳定性的因素进行详细研究,包括吸附能力,热力学和动力学研究。此外,我们已经讨论了将金属离子引入具有更多可替换原子的有机连接基中,这使它们比其他常规吸附剂更可靠。值得注意的是,Zr-MOFs展示了其作为一种经济高效,生态友好的方法以及用于水处理的有趣的吸附剂-吸附剂相互作用的新兴平台。

更新日期:2020-09-16
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