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Luminescence investigation of red-emitting Sr2MgMoO6:Eu3+ phosphor for visualization of latent fingerprint
Journal of Colloid and Interface Science ( IF 9.9 ) Pub Date : 2020-09-16 , DOI: 10.1016/j.jcis.2020.09.024
Yu Wang 1 , Yuee Ke 1 , Shanshan Chen 1 , Junmeng Luo 1 , Shuang Shu 1 , Jing Gao 1 , Bin Deng 2 , Ruijin Yu 1
Affiliation  

Fingerprints are widely studied due to their unique shape and lifelong properties. The latent fingerprint (LFP) visualization is critical in identifying crime scenes and personal information. At present, the powder dusting method for LFP detection is favored due to its environmental friendliness and nontoxicity. However, this method has low resolution, low sensitivity, and large background interference. To address these shortcomings, the red-emitting Sr2MgMoO6:xEu3+ (x = 0–0.50) phosphors were synthesized using the solid-state reaction process. The products were systematically studied through the structural phase, luminescent property, decay curve, and color purity. Sr2MgMoO6:xEu3+ phosphors were monitored at 596 nm and exhibited a commendable broad excitation band between 250 and 475 nm. This result indicated that the disadvantage of the poor absorption of commercial red phosphors (Y2O2S:Eu3+) in the near-ultraviolet region was overcome. Under excitation at 393 nm, the synthesized Sr2MgMoO6:Eu3+ phosphor exhibited intense red light at 596 and 616 nm, due to the 5D0 → 7F1 and 5D0 → 7F2 transitions of Eu3+ ions. The optimal concentration for the Sr2MgMoO6:xEu3+ phosphor was x = 20 mol%, and the concentration quenching effect was ascribed to the dipole–dipole interaction. The Commission International del′Eclairage (CIE) chromaticity coordinates of Sr2MgMoO6:Eu3+ were (0.643, 0.356), and the color purity was 99.8%. Furthermore, the fluorescent LFP images developed by Sr2MgMoO6:0.20Eu3+ phosphors were well visualized, and level 1–3 details were well identified with high resolution, contrast, sensitivity, and selectivity. The obtained results suggested that the Sr2MgMoO6:Eu3+ phosphor can be applied for LFP detection.



中文翻译:

用于潜在指纹可视化的发红光的Sr 2 MgMoO 6:Eu 3+荧光粉的发光研究

指纹因其独特的形状和终身特性而被广泛研究。潜在指纹(LFP)可视化对于识别犯罪现场和个人信息至关重要。目前,用于LFP检测的粉末除尘方法由于其环境友好和无毒而受到青睐。但是,该方法分辨率低,灵敏度低,背景干扰大。为了解决这些缺点, 使用固态反应过程合成了发红光的Sr 2 MgMoO 6x Eu 3+x = 0-0.50)荧光粉。通过结构相,发光性质,衰减曲线和色纯度系统地研究了产物。锶2 MgMoO6x Eu 3+磷光体在596 nm处进行监测,并在250至475 nm之间显示出值得称赞的宽激发带。该结果表明,克服了在近紫外线区域中商业红色磷光体(Y 2 O 2 S:Eu 3+)吸收差的缺点。在393 nm激发下,由于5 D 0  →  7 F 15 D 0  →  7 F 2,合成的Sr 2 MgMoO 6:Eu 3+荧光粉在596和616 nm处显示出强烈的红光。Eu 3+离子的跃迁。Sr 2 MgMoO 6x Eu 3+荧光粉的最佳浓度为x  = 20 mol%,并且浓度猝灭效应归因于偶极-偶极相互作用。Sr 2 MgMoO 6:Eu 3+的Commission International del'Eclairage(CIE)色度坐标为(0.643,0.356 ),色纯度为99.8%。此外,由Sr 2 MgMoO 6:0.20Eu 3+显影的荧光LFP图像荧光粉清晰可见,并以高分辨率,对比度,灵敏度和选择性很好地识别了1-3级细节。获得的结果表明,Sr 2 MgMoO 6:Eu 3+荧光粉可用于LFP检测。

更新日期:2020-09-25
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