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Structural, spectroscopic and optical analysis of green-glowing BaLaAlO4:Er3+ nanomaterials for photonic applications
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-09-16 , DOI: 10.1016/j.cplett.2020.138004
Priyanka Sehrawat , Avni Khatkar , Priti Boora , Sonika Singh , Mukesh Kumar , R.K. Malik , S.P. Khatkar , V.B. Taxak

New alluring features of green-glowing BaLaAlO4:Er3+ nanomaterials fabricated via facile solution combustion method, have been discussed. Crystallographic data was analyzed by X-ray diffraction and Rietveld refinement. When excited by 379 nm near ultraviolet (NUV) light, the phosphors exhibited vivid-green luminescence (548 nm). Emission intensity reached maximum at 2.0 mol% amount of Er3+ ions, above which luminescence was quenched via d-d (dipole–dipole) interrelations. Lastly, color coordinates of nanopowders (0.211, 0.402) resided in green region & corresponded to standard EBU coordinates, which endorsed them a promising green-glowing component in the innovative photonic devices i.e., NUV-pumped white-LEDs (light emitting diodes) and photovoltaic cells.



中文翻译:

用于光子应用的绿色发光BaLaAlO 4:Er 3+纳米材料的结构,光谱和光学分析

讨论了通过溶液熔解法制备的绿色发光BaLaAlO 4:Er 3+纳米材料的新诱人特性。晶体学数据通过X射线衍射和Rietveld精制分析。当通过379 nm的近紫外(NUV)光激发时,磷光体显示出鲜艳的绿色发光(548 nm)。当Er 3+离子的含量为2.0 mol%时,发射强度达到最大值,在此之上,通过dd(偶极-偶极)相互关系淬灭了发光。最后,纳米粉(0.211,0.402)的色坐标位于绿色区域并与标准EBU坐标相对应,这表明纳米粉在创新的光子器件中是有希望的绿色发光成分,例如NUV泵浦的白光LED(发光二极管)和光伏电池。

更新日期:2020-09-23
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