Cell Reports Physical Science ( IF 7.9 ) Pub Date : 2020-09-16 , DOI: 10.1016/j.xcrp.2020.100210 Martin Rieß , Renée Siegel , Jürgen Senker , Josef Breu
The climate challenge calls for the design of energy-efficient CO2-separation materials. CO2-selective solid physisorbents are characterized by a low energy penalty and enable the most promising and energy-efficient CO2 separation technologies by applying vacuum swing adsorption (VSA). Here, we show that a diammonium-pillared microporous organically pillared layered silicate 7 (MOPS-7) represents a CO2-selective physisorbent, synthesized by simple ion exchange of an inexpensive clay. This MOPS provides high dynamic, reversible, and reproducible CO2 uptakes and selectivities proven in dynamic breakthrough experiments mimicking flue gas, natural gas, and biogas conditions. The selective interaction with CO2 is dominated by the multipole interactions with the microporous hybrid material. Thus, the energy penalty attributed to regeneration is intrinsically reduced. The simplicity and modularity of pillaring low-budget and environmentally friendly clays, combined with industrially capable performance with respect to thermal stability, high dynamic CO2 adsorption selectivity, and energy-efficient restoration renders MOPS-7 a highly attractive CO2 adsorbent.
中文翻译:
具有动态CO 2选择性的二柱毛MOPS
气候挑战要求设计节能的CO 2分离材料。CO 2选择性固体吸附剂的特点是能量损失低,并且通过应用真空摆动吸附(VSA)可以实现最有前途和最节能的CO 2分离技术。在这里,我们表明,二铵柱状微孔有机柱状层状硅酸盐7(MOPS-7)代表通过简单的廉价粘土离子交换合成的CO 2选择性物理吸附剂。这种MOPS具有高动态,可逆和可再现的CO 2吸收率和选择性,在模拟烟道气,天然气和沼气条件的动态突破实验中得到了证明。与CO的选择性相互作用2与微孔杂化材料的多极相互作用占主导。因此,固有地减少了归因于再生的能量损失。带支柱的低成本和环保型粘土的简单性和模块化,再加上热稳定性,高动态CO 2吸附选择性和节能修复方面的工业性能,使MOPS-7成为极具吸引力的CO 2吸附剂。