“Eggs in egg cartons”: co-crystallization to embed molecular cages into crystalline lattices,Chemical Science

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“Eggs in egg cartons”: co-crystallization to embed molecular cages into crystalline lattices
Chemical Science ( IF 7.6 ) Pub Date : 2020-09-15 , DOI: 10.1039/d0sc03191g
Yuya Domoto ₁ , Masahiro Abe ₁ , Kidai Yamamoto ₁ , Takashi Kikuchi ₂ , Makoto Fujita _{1,

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Affiliation

Discrete (M₃L₂)_n cages assembled from a tripodal ligand (L) and metal ions (M: Cu(I) or Ag(I)) are embedded in networked coordination hosts formed by partial dissociation of the same discrete cages during the crystallization process. The resulting “eggs-in-an-egg-carton” structures provide unique examples of the co-crystallization of discrete and infinite coordination frameworks.

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