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Photo-assisted splitting of water into hydrogen using visible-light activated silver doped g-C3N4 & CNTs hybrids
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2020-09-15 , DOI: 10.1016/j.ijhydene.2020.08.191
Tehmeena Ishaq , Maryam Yousaf , Ijaz Ahmad Bhatti , Muhammad Ahmad , Mujtaba Ikram , Muhammad Usman Khan , Ayesha Qayyum

Herein, highly efficient and cost effective solar photocatalytic water splitting for hydrogen (H2) generation was achieved by modified g-C3N4. Visible light absorption of g-C3N4 was enhanced by decorating g-C3N4 matrix with silver nanoparticles (Ag). Moreover, incorporation of carbon nanotubes (CNTs) in Ag/g-C3N4 facilitated photocatalytic performance through efficient separation and transfer of photogenerated e-h pairs (charges) in Ag/g-C3N4 that consequently generated very pure and significant H2. Among several tested ratios (wt. %) of Ag/g-C3N4/CNTs, 1.82 (Ag/g-C3N4) and 2.00 (and Ag/g-C3N4/CNTs) were found to be highly efficient that harvested maximum visible-light and produced H2 @1.48 mmol h−1 and 1.78 mmol h−1. We witnessed distinctive role of CNTs as an electron collector and carrier to separate photogenerated e-h pairs to facilitate photocatalysis for H2 generation together with possible utility of Ag and CNTs doped materials with regard to energy transformation.



中文翻译:

使用可见光活化的掺杂银的gC 3 N 4和CNTs杂化物光辅助将水分解为氢

在此,通过改性的gC 3 N 4,实现了用于产生氢气(H 2)的高效且具有成本效益的太阳能光催化水分解。通过用银纳米颗粒(Ag)装饰gC 3 N 4基质,可以提高gC 3 N 4的可见光吸收率。此外,将碳纳米管(CNT)掺入Ag / gC 3 N 4中可通过有效分离和转移Ag / gC 3 N 4中的光生eh对(电荷)来促进光催化性能,从而产生非常纯净和显着的H 2。在Ag / gC 3 N 4 / CNTs的几个测试比率(wt。%)中,发现1.82(Ag / gC 3 N 4)和2.00(以及Ag / gC 3 N 4 / CNTs)是高效的,收获量最大。可见光并产生H 2 @ 1.48 mmol h -1和1.78 mmol h -1。我们目睹了CNTs作为电子收集器和载体的独特作用,以分隔光生的eh对以促进光催化H 2生成,以及在能量转换方面可能使用了Ag和CNTs掺杂的材料。

更新日期:2020-11-02
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