Abstract

Functionalization of methylenebis(naphthalene-2-ol/-2,7-diol) and rccc-resorcincalix[4]arene has given a series of their derivatives at the OH groups with 1, 2, or 4 pairs of chelate ionophore substituents differing in the combination of the constituting electron-donating atoms (O, S , N, P). The effect of the structural features of the ligand on its ability to recognize and bind transition metals cations (Cd²⁺, Ag⁺, Hg²⁺) has been studied by means of liquid extraction.

中文翻译：

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二萘甲基甲烷和间苯二酚[4]芳烃的多官能螯合物衍生物：螯合物结构及其受体能力的合成与关系

摘要

亚甲基双（萘-2-醇/ -2,7-二醇）和rccc-间苯二酚杯[4]芳烃的官能化已在OH基上提供了一系列衍生物，它们分别具有1对，2对或4对螯合离子载体取代基组成给电子原子（O，S，N，P）的组合。通过液体萃取研究了配体的结构特征对其识别和结合过渡金属阳离子（Cd 2 ⁺，Ag ⁺，Hg ²⁺）的能力的影响。