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Synthesis of Porous Ceramic Materials for Catalytically Active Membranes by Technological Combustion and Sintering
Glass and Ceramics ( IF 0.6 ) Pub Date : 2020-09-15 , DOI: 10.1007/s10717-020-00275-8
V. I. Uvarov , R. D. Kapustin , A. S. Fedotov , A. O. Kirillov

A porous, catalytically active membrane based on coarse-fraction silicon carbide was synthesized. Ultrafine additives with an eutectic composition of magnesium oxide and silicon carbide, which during sintering at temperatures from 1100 to 1450°C form a liquid phase in the form of clinoenstatite MgSiO3 that wets the coarse-size SiC particles and forms a strong porous framework of the membrane, were introduced into the initial SiC powder to synthesize the membranes. The pore size of the ceramic material was studied as a function of the pressing pressure, which made it possible to obtain a highly porous ceramic membrane with pore size optimized for dehydrogenation of ethylbenzene into styrene. Modification of the pore surfaces to 10% Re – W by means of active components using the alkoxy method is performed in order to give the synthesized membrane the catalytic properties required for realizing the dehydrogenation process.



中文翻译:

燃烧烧结合成催化活性膜多孔陶瓷材料。

合成了一种基于粗级碳化硅的多孔催化活性膜。具有氧化镁和碳化硅的低共熔组成的超细添加剂,在1100至1450°C的温度下烧结时,形成斜长辉石MgSiO 3形式的液相将润湿粗大的SiC颗粒并形成坚固的多孔膜框架的方法引入到最初的SiC粉末中以合成膜。研究了陶瓷材料的孔径与压制压力的关系,从而有可能获得一种高度多孔的陶瓷膜,其孔径经优化可用于乙苯脱氢成苯乙烯。为了使合成膜具有实现脱氢过程所需的催化性能,使用烷氧基方法通过活性成分将孔表面改性为10%Re-W。

更新日期:2020-09-15
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