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Controllable Phosphorylation of Thioesters: Selective Synthesis of Aryl and Benzyl Phosphoryl Compounds.
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2020-09-14 , DOI: 10.1021/acs.joc.0c01557 Kaiqiang Xu 1 , Long Liu 1 , Zhaohui Li 1 , Tianzeng Huang 1 , Kang Xiang 1 , Tieqiao Chen 1
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2020-09-14 , DOI: 10.1021/acs.joc.0c01557 Kaiqiang Xu 1 , Long Liu 1 , Zhaohui Li 1 , Tianzeng Huang 1 , Kang Xiang 1 , Tieqiao Chen 1
Affiliation
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The controllable phosphorylations of thioesters were developed. When the reaction was catalyzed by a palladium catalyst, aryl or alkenyl phosphoryl compounds were generated through decarbonylative coupling, while the benzyl phosphoryl compounds were produced through deoxygenative coupling when the reaction was carried out in the presence of only a base.
中文翻译：
硫酯的可控磷酸化：芳基和苄基磷酰基化合物的选择性合成。
开发了可控制的硫酯磷酸化。当反应由钯催化剂催化时，当仅在碱的存在下进行反应时，芳基或烯基磷酰基化合物通过脱羰偶合产生，而苄基磷酰基化合物通过脱氧偶合产生。
更新日期：2020-11-21
中文翻译：
硫酯的可控磷酸化：芳基和苄基磷酰基化合物的选择性合成。
开发了可控制的硫酯磷酸化。当反应由钯催化剂催化时，当仅在碱的存在下进行反应时，芳基或烯基磷酰基化合物通过脱羰偶合产生，而苄基磷酰基化合物通过脱氧偶合产生。
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