All-solid-state polymeric electrochromic devices (ECDs) were fabricated based on anodic poly(4,4′,4″-tris[4-(2-bithienyl)phenyl]amine) (PTBTPA) and cathodic poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS). PEDOT:PSS films with various thicknesses were obtained to control their charge capacities and neutral transmittances. It is found that the compatibility between PTBTPA and PEDOT:PSS has an important influence on the driving potential and electrochromic properties of ECDs. Therefore, an ECD with well-matched color and charge capacity between PTBTPA and PEDOT:PSS exhibits excellent electrochromic properties under low driving potential ranges (0–1.4 V) with high optical contrast of 54.3%, fast switching time of 1.02 s (colored time) and 0.51 s (bleached time), large coloration efficiency of 812.1 cm²‧C⁻¹ and good cycling stability (which retains 70.2% of its original optical contrast after 10,000 cycles). The optimized all-solid-state polymeric ECD has potential applications in smart windows, electronic-tags and rearview mirrors.

基于阳极聚（4,4'，4''-三[4-（2-（2-噻吩基）苯基]胺）（PTBTPA）和阴极聚（3,4-）制备全固态聚合物电致变色器件（ECD）乙二氧基噻吩）：聚苯乙烯磺酸盐（PEDOT：PSS）。获得了各种厚度的PEDOT：PSS薄膜，以控制其电荷容量和中性透射率。发现PTBTPA和PEDOT：PSS之间的相容性对ECD的驱动电势和电致变色性能具有重要影响。因此，在PTBTPA和PEDOT：PSS之间具有良好匹配的颜色和电荷容量的ECD在低驱动电势范围（0-1.4 V）下具有出色的电致变色性能，具有54.3％的高光学对比度，1.02 s的快速切换时间（着色时间） ）和0.51 s（漂白时间），显色效率高达812.1 cm ²‧C ^-1和良好的循环稳定性（在10,000次循环后保留其原始光学对比度的70.2％）。经过优化的全固态聚合物ECD在智能窗户，电子标签和后视镜中具有潜在的应用。