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Synthesis, crystal structure and photoluminescence properties of high-color-purity red-emitting SrLu2O4:Eu3+ phosphors with excellent thermal stability
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2020-09-14 , DOI: 10.1016/j.jphotochem.2020.112908
Xiaoyong Huang , Liangling Sun , Balaji Devakuma

Red-emitting SrLu2O4:Eu3+ phosphors were prepared by a high-temperature solid-state reaction approach, and they were characterized by X-ray diffraction (XRD), excitation and emission spectra, luminescence decay lifetimes, CIE chromaticity coordinates, and temperature-dependent emission spectra. Rietveld refinement of XRD pattern revealed that the SrLu2O4:Eu3+ phosphors crystallized into orthorhombic crystal system with a space group of Pnma and cell parameters of a = 9.962(1) Å, b = 3.343(5) Å, c = 11.746(2) Å, α = β = γ = 90°, and V = 391.24(3) Å3. Under 395 nm excitation, these SrLu2O4:Eu3+ phosphors showed intense red emissions in the 550-750 nm wavelength range with peaks around 581, 593, 611, 653, and 708 nm, corresponding to the 5D07FJ (J = 0-4) transitions of Eu3+ ions. Investigation on Eu3+ doping concentration dependent emission spectra demonstrated the critical quenching concentration of Eu3+ ions was 9 mol%. The luminescence decay lifetimes declined from 1.77 to 1.51 ms with increasing Eu3+ concentration from 1 to 10 mol%. Notably, the CIE chromaticity coordinates (0.646, 0.354) of composition-optimal SLO:9%Eu3+ phosphors were close to the standard red light (0.67, 0.33), and its color purity reached as high as 94.1%. Finally, it was found that the SLO:9%Eu3+ phosphors also had excellent thermal stability and color stability at higher temperatures. The emission intensity at 423 K was dropped to 89% of that at 303 K, and the activated energy of thermal quenching was 0.32 eV.



中文翻译:

具有出色热稳定性的高色纯度发红光SrLu 2 O 4:Eu 3+荧光粉的合成,晶体结构和光致发光性能

通过高温固态反应方法制备了红色发光的SrLu 2 O 4:Eu 3+荧光粉,并通过X射线衍射(XRD),激发和发射光谱,发光衰减寿命,CIE色度坐标对其进行了表征。以及与温度有关的发射光谱。XRD图案的Rietveld精炼显示,SrLu 2 O 4:Eu 3+荧光粉结晶成正交晶体系统,其空间群为Pnma,单元参数为a  = 9.962(1)Å,b  = 3.343(5)Å,c  = 11.746(2)Å,α=β=γ= 90 °,和V = 391.24(3)3。在395 nm激发下,这些SrLu 2 O 4:Eu 3+荧光粉在550-750 nm波长范围内显示出强烈的红色发射,峰值在581、593、611、653和708 nm左右,对应于5 D 07 Eu 3+离子的F J(J = 0-4)跃迁。Eu 3+掺杂浓度依赖性发射光谱的研究表明,Eu 3+离子的临界猝灭浓度为9 mol%。随着Eu 3+的增加,发光衰减寿命从1.77降低到1.51 ms浓度为1至10 mol%。值得注意的是,组成最佳的SLO:9%Eu 3+荧光粉的CIE色度坐标(0.646,0.354)接近标准红光(0.67,0.33 ),其色纯度高达94.1%。最后,发现SLO:9%Eu 3+荧光粉在高温下也具有出色的热稳定性和颜色稳定性。423 K时的发射强度降至303 K时的89%,热猝灭的活化能为0.32 eV。

更新日期:2020-09-14
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