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Numerical modeling and optimization of product selectivity and catalyst activity in Fischer-Tropsch synthesis via response surface methodology: Cobalt carbide particle size and H2/CO ratio effects
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2020-09-14 , DOI: 10.1016/j.ijhydene.2020.08.219
Nurlan Amirov , Amir Reza Vakhshouri

The effects of cobalt carbide (Co2C) catalyst particle size and usage ratio (H2/CO) on the Fischer-Tropsch selectivity, cobalt time yield and turnover frequency were investigated through statistical modeling by means of response surface methodology based on the data obtained over seven SiO2 supported cobalt catalysts at three different usage ratio levels. The effects of predictor variables on responses are illustrated in contour and surface plots and analyzed based on both model equation and plots. C5+ selectivity was found to increase with increasing Co2C particle size up to the range of 9.6–11.75 nm, after which decreases slightly. Furthermore, a linear relationship was detected between CH4 selectivity and C5+ selectivity for predicted data at all H2/CO ratios (0.5–2) in the Co2C particle size range of 5.3–9.4 nm. Multi-objective optimization conducted for the enhancement of C5+ selectivity predicted the particle size of 6.795 nm and usage ratio of 0.500 as optimum conditions.



中文翻译:

费-托合成中通过响应面方法进行数值建模和优化产物选择性和催化剂活性的方法:碳化钴粒度和 H2/CØ 比率效应

碳化钴的作用(CØ2C)催化剂的粒径和使用率(H2/CØ费-托选择性,通过基于响应面法的统计模型,基于七个以上的数据,研究了钴的时间产量和周转频率 小号一世Ø2在三种不同的使用率水平下负载的钴催化剂。预测变量对响应的影响在等高线和曲面图中进行了说明,并基于模型方程式和图进行了分析。发现C 5+的选择性随着增加而增加CØ2C粒径可达9.6-11.75 nm,此后略有减小。此外,检测到CH 4选择性和C 5+选择性之间的线性关系H2/CØ 比率(0.5–2)在 CØ2C粒径范围为5.3–9.4 nm。为提高C 5+选择性而进行的多目标优化预测最佳条件为6.795 nm的粒径和0.500的使用率。

更新日期:2020-11-02
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