Materials Research Letters ( IF 8.6 ) Pub Date : 2019-07-24 , DOI: 10.1080/21663831.2019.1644684 Andrejs Petruhins 1 , Jun Lu 1 , Lars Hultman 1 , Johanna Rosen 1
We report the synthesis of eight new members of the i-MAX family, of the formula (Mo2/3RE1/3)2GaC, where RE = Gd, Tb, Dy, Ho, Er, Tm, Lu, and Yb, the latter not previously incorporated in a MAX phase. The structure and composition of powder samples were investigated by X-ray diffraction, scanning transmission electron microscopy, and energy dispersive X-ray analysis combined with scanning electron microscopy. All phases showed evidence of an orthorhombic (Cmcm) structure, and the phases based on Er and Yb also crystallized in a monoclinic (C2/c) arrangement. The chemical order of the magnetic elements suggests interesting magnetic characteristics, with a high tuning potential through the range of attainable lanthanide elements.
中文翻译:
原子层状化学有序稀土(RE)i -MAX相的合成;(Mo 2/3 RE 1/3)2 GaC(RE = Gd,Tb,Dy,Ho,Er,Tm,Yb和Lu
我们报告了i -MAX家族的八个新成员的合成,其分子式为(Mo 2/3 RE 1/3)2 GaC,其中RE = Gd,Tb,Dy,Ho,Er,Tm,Lu和Yb ,后者先前未纳入MAX阶段。通过X射线衍射,扫描透射电子显微镜和能量色散X射线分析结合扫描电子显微镜研究了粉末样品的结构和组成。所有相均显示出正交晶(Cmcm)结构的证据,并且基于Er和Yb的相也在单斜晶(C 2 / c)的安排。磁性元素的化学顺序表明了有趣的磁性,在可实现的镧系元素范围内具有很高的调谐电位。