Abstract

The mechanisms of acetylene vapour-phase hydrochlorination over chloro complexes of noble metals were reviewed. The nature of the active sites of heterogeneous catalysts, isotope effects of HCl/DCl, stereochemistry of reaction products, possible stepwise mechanisms, and mechanisms of individual steps were considered.

中文翻译：

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乙炔催化氯化氢的机理：活性位，同位素效应和立体选择性。

摘要

综述了乙炔气相气相氯化法制备贵金属氯配合物的机理。考虑了非均相催化剂活性位点的性质，HCl / DCl的同位素效应，反应产物的立体化学，可能的逐步机理以及各个步骤的机理。