This review article summarizes recent work in developing hybrid photocatalysts by grafting molecular catalysts on solid-state surfaces for solar CO₂ reduction. Several surface-immobilized systems are discussed to examine effects of ligand derivatization and surface characteristics on the activities of hybrid photocatalysts. This article also describes the extensive use of spectroscopic techniques in studying hybrid photocatalysts, and briefly introduces research efforts in constructing artificial photosynthetic assemblies based on surface-immobilized CO₂-reduction catalysts.

中文翻译：

---

使用表面固定的分子催化剂减少太阳能CO ₂

这篇综述文章总结了通过在固态表面上接枝分子催化剂以减少太阳能CO ₂来开发混合光催化剂的最新工作。讨论了几种表面固定化系统，以研究配体衍生化和表面特性对杂化光催化剂活性的影响。本文还描述了光谱技术在研究混合光催化剂中的广泛应用，并简要介绍了基于表面固定化CO ₂还原催化剂构建人工光合组件的研究工作。