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The regulating mechanism of MgCO3·3H2O whisker growth orientation with the presence of SDS
Journal of CO2 Utilization ( IF 7.2 ) Pub Date : 2020-09-13 , DOI: 10.1016/j.jcou.2020.101307
Xi Geng , Li Lv , Tao Zhang , Shengwei Tang

CO2 mineralization is an effective route to reduce CO2 emission. But the commercialization of CO2 mineralization process is impeded by the poor or even negative profit. MgCO3·3H2O whisker was prepared by indirect CO2 mineralization of MgSO4-(NH4)2CO3 in the presence of Sodium Dodecyl Sulfate (SDS) to improve the profit. MgCO3·3H2O whisker with an average length of 40 μm, average diameter of 1 μm, and aspect ratio as big as 40 was successfully prepared with the presence of SDS. SEM, AFM, XRD and TGA were used to characterize the morphology and structure of MgCO3·3H2O whisker, and XPS was used to characterize the compositions of MgCO3·3H2O crystal planes. The regulating mechanism of MgCO3·3H2O whisker growth orientation was studied systematically. The SDS ionizes CH3(CH2)11-OSO3- in the solution, and then combines with the active site Mg2+ complex on the crystal plane in the [100] direction. The (CH3(CH2)11-OSO3)2Mg faces the liquid phase with the hydrophobic group CH3(CH2)11-, which separates the [100] direction from the liquid phase, hindering the growth of the [100] direction crystal plane. Therefore, MgCO3·3H2O whisker is oriented and grows easily on the [010] direction with high aspect ratio.



中文翻译:

SDS存在下MgCO 3 ·3H 2 O晶须生长取向的调控机制

CO 2矿化是减少CO 2排放的有效途径。但是,CO 2矿化过程的商业化受到利润不佳甚至是负利润的阻碍。MgCO 3 ·3H 2 O晶须是通过在十二烷基硫酸钠(SDS)存在下间接将MgSO 4-(NH 42 CO 3的CO 2矿化制备的,以提高利润。碳酸镁3 ·3H 2在SDS的存在下,成功制备了平均长度为40μm,平均直径为1μm,纵横比最大为40的O晶须。SEM,AFM,XRD和TGA表征MgCO 3 ·3H 2 O晶须的形貌和结构,XPS表征MgCO 3 ·3H 2 O晶面的组成。系统研究了MgCO 3 ·3H 2 O晶须生长取向的调控机理。的SDS电离CH 3(CH 211 -OSO 3 -中的溶液中,然后结合的活性位点的Mg 2+在[100]方向的晶体平面上的复合物。(CH 3(CH 211 -OSO 32 Mg面对具有疏水基团CH 3(CH 211-的液相,该疏水基团将[100]方向与液相分隔开,从而阻碍了[ 100]方向晶面。因此,MgCO 3 ·3H 2 O晶须取向并以高纵横比容易在[010]方向上生长。

更新日期:2020-09-13
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