One‐pot synergistic/cascade reactions represent a promising direction for future catalysis. In particular, the use of solar light to initiate the synergistic/cascade reactions in one pot has attracted increasing attention, with the aim of developing renewable energy–based processes. Metal–organic frameworks (MOFs), are considered to be a promising type of multifunctional catalysts for light‐initiated synergistic/cascade catalysis, due to their excellent photoactive activity and unique structural characteristics, which enable the incorporation of functionally different catalytic active sites to work in concert. Herein, some recent developments on using MOFs as multifunctional catalysts for light‐initiated one‐pot synergistic/cascade reactions are summarized. This review starts with general background information on synergistic/cascade catalysis and the possibility of using MOFs as multifunctional catalysts for light‐initiated synergistic/cascade reactions. Then some examples of designing and fabricating of multifunctional MOFs, including single MOFs, doped MOFs, and metal nanoparticles (MNPs)/MOFs, for a variety of light‐initiated one‐pot synergistic/cascade reactions are demonstrated. Finally, the challenges and the perspective of the development of multifunctional MOFs for light‐induced one‐pot synergistic/cascade reactions are addressed. It is hoped that this review can stimulate future research on the designing and developing of more smart multifunctional MOFs for light‐initiated one‐pot synergistic/cascade reactions.

中文翻译：

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金属有机框架上可见光引发的协同/级联反应

单锅协同/级联反应代表了未来催化的有希望的方向。尤其是，利用太阳光在一锅中引发协同/级联反应已引起越来越多的关注，其目的是发展基于可再生能源的工艺。金属有机骨架（MOF）被认为是光引发的协同/级联催化的有前途的多功能催化剂，因为它们具有出色的光活性和独特的结构特征，可以整合功能不同的催化活性位来发挥作用在演唱会。在此，总结了使用MOF作为光引发单锅协同/级联反应的多功能催化剂的最新进展。这篇综述从关于协同/级联催化的一般背景信息以及将MOF用作光引发的协同/级联反应的多功能催化剂的可能性开始。然后展示了设计和制造多功能MOF的一些示例，包括单个MOF，掺杂的MOF和金属纳米颗粒（MNP）/ MOF，用于各种光引发的单锅协同/级联反应。最后，讨论了针对光诱导的一锅协同/级联反应开发多功能MOF的挑战和前景。希望这篇评论能够激发未来对设计和开发更智能的多功能MOF的研究，这些MOF用于光引发的单锅协同/级联反应。