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Effects of TiO2 doping on microstructure and properties of directed laser deposition alumina/aluminum titanate composites
Virtual and Physical Prototyping ( IF 10.6 ) Pub Date : 2019-05-30 , DOI: 10.1080/17452759.2019.1622987
Dongjiang Wu 1 , Yunfei Huang 1 , Fangyong Niu 1 , Guangyi Ma 1 , Shuai Yan 1 , Chaojiang Li 2 , Jun Ding 2
Affiliation  

Al2O3-based composite ceramics have excellent high temperature performance and are ideal materials for preparing hot end components. However, poor fracture toughness and thermal shock resistance limit its applications. Based on the excellent low thermal expansion characteristics and thermal shock resistance of Al2TiO5 ceramic, different composition ratios of Al2O3/Al2TiO5 composite ceramics were prepared by directed laser deposition (DLD) technology. Effects of TiO2 doping amount on microstructure and properties of the composite ceramics were investigated. Results show that α-Al2O3 phase is discretely distributed in the continuous aluminum titanate matrix when TiO2 doping amount between 2 and 30 mol%. With the increase of TiO2 doping amount, content of Al2O3 gradually decreases and its morphology changes from cellular to dendritic. When TiO2 doping amount reaches 43.9 mol%, the microstructure transforms into fine Al2TiO5/Al6Ti2O13 eutectic structure. Property test results show that Al2O3/Al2TiO5 composite ceramics have good comprehensive mechanical properties when TiO2 doping amount between 2 and 6 mol%.



中文翻译:

TiO 2掺杂对定向激光沉积氧化铝/钛酸铝复合材料组织和性能的影响

Al 2 O 3基复合陶瓷具有优异的高温性能,是制备热端部件的理想材料。然而,差的断裂韧性和耐热冲击性限制了其应用。基于Al 2 TiO 5陶瓷优异的低热膨胀特性和耐热冲击性,通过定向激光沉积(DLD)技术制备了不同组成比的Al 2 O 3 / Al 2 TiO 5复合陶瓷。研究了TiO 2掺杂量对复合陶瓷组织和性能的影响。结果表明,α-Al系2 ö3相离散分布在连续的钛酸铝基质的TiO时2之间2和30摩尔%的掺杂量。随着TiO 2掺杂量的增加,Al 2 O 3的含量逐渐降低,其形态从蜂窝状变为树枝状。当TiO 2掺杂量达到43.9mol%时,显微组织转变成精细的Al 2 TiO 5 / Al 6 Ti 2 O 13共晶结构。性能测试结果表明,Al 2 O 3 / Al 2 TiO 5当TiO 2的掺杂量为2至6 mol%时,复合陶瓷具有良好的综合机械性能。

更新日期:2019-05-30
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