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Electrochemically Induced Diels‐Alder Reaction: An Overview
The Chemical Record ( IF 7.0 ) Pub Date : 2019-08-19 , DOI: 10.1002/tcr.201900018
Majid M. Heravi 1 , Vahideh Zadsirjan 1 , Elham Kouhestanian 1 , Behnoush AlimadadiJani 1
Affiliation  

One of the most important name reactions in organic chemistry, is the Diels‐Alder cycloaddition reaction. It is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile to construct a substituted cyclohexene derivative. It is the stereotypical example of a pericyclic reaction with a concerted mechanism. In synthesis, the use of electricity instead of stoichiometric amounts of oxidant or reducing agents is definitely appealing for economic, ecological and selective, reasons. In this review, we try to underscore the combination of the electrosynthesis with Diels‐Alder cycloaddition reaction to establish of a powerful synthetic tool which may encourage synthetic organic chemists to use it in the future.

中文翻译:

电化学诱导的Diels-Alder反应:概述

Diels-Alder环加成反应是有机化学中最重要的名称反应之一。这是共轭二烯与取代烯烃之间的化学反应,通常被称为亲二烯体,以构建取代的环己烯衍生物。这是具有协同机制的周环反应的典型例子。在合成中,出于经济,生态和选择性的原因,使用电代替化学计量的氧化剂或还原剂绝对有吸引力。在这篇综述中,我们试图强调电合成与Diels-Alder环加成反应的结合,以建立强大的合成工具,这可能会鼓励合成有机化学家将来使用它。
更新日期:2019-08-19
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