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Modified graphene nanoplatelet and epoxy/block copolymer-based nanocomposite: physical characteristic and EMI shielding studies
Nanocomposites ( IF 4.2 ) Pub Date : 2016-09-28 , DOI: 10.1080/20550324.2016.1236535
Zanib Anwar 1 , Ayesha Kausar 1 , Laraib A. Khan 2 , Bakhtiar Muhammad 3
Affiliation  

In this research work, diglycidyl ether of bisphenol-A (DGEBA) and polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene (PSPEB) were blended and loaded with purified graphene nanoplatelet (GNP-P) and acid-functionalized graphene nanoplatelet (GNP-F). Solution mixing route was used for nanocomposite processing with diaminodiphenylmethane as a hardener. According to SEM, inclusion of functional GNP-F depicted fine morphology due to interfacial adhesion between functional nanofiller and blend. Sharp increase in ultimate tensile strength and toughness was observed for DGEBA/PSPEB/GNP-F 0.03–0.1 system, i.e. 60.4–64.5 MPa and 422.6–725.5 MPa, respectively. For 0.1 wt.% GNP-P loading, Tmax was observed as 547 °C; whereas, GNP-F showed higher value of 568 °C. Glass transition temperature of acid functional system was also higher (258 °C) than purified one (229 °C). DGEBA/PSPEB/GNP-F 0.1 depicted semi-crystalline nature (12.5° and 19.1°). EMI shielding effectiveness of nanocomposite was sufficiently high in the range of ~17.9–20.07 dB, i.e. desired for aerospace applications. Moreover, introduction of 0.1 wt.% functional graphene nanoplatelet enhanced the electrical conductivity up to 0.14 cm−1.



中文翻译:

改性石墨烯纳米片和基于环氧/嵌段共聚物的纳米复合材料:物理特性和EMI屏蔽研究

在本研究工作,双酚-A(DGEBA)的二环氧甘油醚和聚苯乙烯-嵌段-聚(乙烯- RAN丁烯) -嵌段-聚苯乙烯(PSPEB)混合并装载有纯化的石墨烯纳米薄片(GNP-P)和酸功能化石墨烯纳米血小板(GNP-F)。溶液混合路线用于以二氨基二苯甲烷为硬化剂的纳米复合材料加工。根据SEM,由于功能性纳米填料和共混物之间的界面粘合,功能性GNP-F的包容表现出良好的形貌。DGEBA / PSPEB / GNP-F 0.03-0.1体系的极限抗拉强度和韧性急剧增加,分别为60.4-64.5 MPa和422.6-725.5 MPa。对于0.1 wt。%的GNP-P负载,T max观察到为547℃。而GNP-F则显示更高的568°C值。酸官能系统的玻璃化转变温度(258°C)也高于纯化的玻璃化转变温度(229°C)。DGEBA / PSPEB / GNP-F 0.1表示半结晶性质(12.5°和19.1°)。纳米复合材料的EMI屏蔽效果在〜17.9–20.07 dB的范围内足够高,这是航空航天应用所希望的。此外,引入0.1重量%的功能性石墨烯纳米片增强了高达0.14cm -1的电导率。

更新日期:2016-09-28
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