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Structural and Optical Properties of N-Doped and B-Doped Carbon Dots
Journal of Structural Chemistry ( IF 1.2 ) Pub Date : 2020-05-01 , DOI: 10.1134/s0022476620050194
A. E. Tomskaya , I. P. Prosvirin , M. N. Egorova , S. A. Smagulova , I. P. Asanov

Carbon dots (CDs) demonstrate unique luminescence properties due to conjugated π domains of the sp 2 / sp 3 hybridized carbon core, quantum-size effects, and passivation of CD surfaces by functional groups. In this work we present hydrothermal synthesis of nitrogen-doped and boron-doped CDs, their morphological, structural, optical characteristics, and luminescent properties. The CDs are first synthesized from trans- aconitic acid. X-ray photoelectron and infrared spectroscopy data indicate that prepared CDs contain nitrogen and boron atoms. The photoluminescence quantum yield of N-doped and B-doped CDs is 26% and 9%, respectively.

中文翻译:

N 掺杂和 B 掺杂碳点的结构和光学特性

由于 sp 2 / sp 3 杂化碳核的共轭 π 域、量子尺寸效应和官能团对 CD 表面的钝化,碳点 (CD) 表现出独特的发光特性。在这项工作中,我们介绍了氮掺杂和硼掺杂 CD 的水热合成、它们的形态、结构、光学特性和发光特性。CDs 首先由反式乌头酸合成。X 射线光电子和红外光谱数据表明制备的 CD 含有氮和硼原子。N 掺杂和 B 掺杂 CD 的光致发光量子产率分别为 26% 和 9%。
更新日期:2020-05-01
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