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Heterogeneous solar photo-fenton degradation of reactive black 5 using foundry sand and fly ash: value addition to waste
Journal of Environmental Engineering and Landscape Management ( IF 1.0 ) Pub Date : 2016-06-07 , DOI: 10.3846/16486897.2015.1109517
Himadri RAJPUT 1 , Anoop VERMA 1 , Manpreet KAUR 1 , Taranjeet KAUR 2 , Amrit Pal TOOR 2
Affiliation  

This work evaluates the scope of alternative sources of iron i.e. Foundry Sand (FS), Fly Ash (FA) and mixture of FS and FA in heterogeneous photo-Fenton process for the degradation and decolourization of the dye Reactive Black5 (RB5). SEM-EDS characterization of FS and FA confirmed the presence of iron and aluminium which are required for photo-Fenton. In case of FS as an iron source, results confirmed the degradation and decolourization efficiency of 90% in 70 min and 45 min respectively when the reaction parameters were H2O2 = 2.2 mM, FS dose = 0.5 g, pH 3. With FA 90% degradation was achieved within 30 min and 93% decolourization rate within 15 min. When a mixture of FS (0.1 gm) and FA (0.05 gm) is used as source of iron 99% degradation and decolourization of the dye was achieved under the reaction conditions where H2O2 = 2.2 mM, FA:FS = 1:2, pH 3.



中文翻译:

使用铸造砂和粉煤灰的异质太阳光芬顿降解活性黑5:增加废物价值

这项工作评估了铁的替代来源的范围,即铸造砂(FS),粉煤灰(FA)以及FS和FA在异质光Fenton工艺中用于染料活性黑5(RB5)的降解和脱色的混合物。FS和FA的SEM-EDS表征证实了光芬顿所需的铁和铝的存在。在FS为铁源的情况下,结果证实当反应参数为H 2 O 2时,分别在70分钟和45分钟内降解率和脱色效率分别为90%= 2.2mM,FS剂量= 0.5g,pH3。用FA,在30分钟内降解90%,在15分钟内脱色率93%。当使用FS(0.1 gm)和FA(0.05 gm)的混合物作为铁源时,在H 2 O 2 = 2.2 mM,FA:FS = 1的反应条件下,染料的降解和脱色得以实现。 2,pH 3。

更新日期:2016-06-07
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