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Diastereoselective Hydroxyethylation of β‐Hydroxyketones: A Reformatsky Cyclization‐Lactone Reduction Cascade Mediated by SmI2−H2O
Helvetica Chimica Acta ( IF 1.5 ) Pub Date : 2019-11-12 , DOI: 10.1002/hlca.201900227 Monserrat H. Garduño‐Castro 1 , David J. Procter 1
Helvetica Chimica Acta ( IF 1.5 ) Pub Date : 2019-11-12 , DOI: 10.1002/hlca.201900227 Monserrat H. Garduño‐Castro 1 , David J. Procter 1
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The hydroxyethylation of β‐hydroxyketones allows diastereoselective access to important 1,3,5‐triols. The approach exploits a SmI2−H2O‐mediated Reformatsky cyclization‐lactone reduction cascade.
中文翻译:
β-羟基酮的非对映选择性羟乙基化:由SmI2-H2O介导的Reformatsky环化-内酯还原级联反应
的羟乙基化β -hydroxyketones允许重要1,3,5-三醇非对映选择性的访问。该方法利用了SmI 2 -H 2 O介导的Reformatsky环化-内酯还原级联反应。
更新日期:2019-11-12
中文翻译:
β-羟基酮的非对映选择性羟乙基化:由SmI2-H2O介导的Reformatsky环化-内酯还原级联反应
的羟乙基化β -hydroxyketones允许重要1,3,5-三醇非对映选择性的访问。该方法利用了SmI 2 -H 2 O介导的Reformatsky环化-内酯还原级联反应。