Synthesis and Characterization of a Novel Bis‐Sulfoxide and Its Evaluation as a Ligand in p‐Block Chemistry,European Journal of Inorganic Chemistry

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Synthesis and Characterization of a Novel Bis‐Sulfoxide and Its Evaluation as a Ligand in p‐Block Chemistry
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2020-09-11 , DOI: 10.1002/ejic.202000728
Noémi Deak ₁ , Olivier Thillaye du Boullay ₂ , Sonia Mallet-Ladeira ₃ , Ionuț-Tudor Moraru ₄ , David Madec ₃ , Gabriela Nemes ₅

Affiliation

A new aryl bis‐sulfoxide derivative was designed, synthetized and structurally characterized in solution and in solid state. The chemical behaviour of the newly obtained 1,3‐(para‐tolylsulfinyl)‐5‐tert‐butyl‐benzene 2 was evaluated towards tin, silicon and phosphorus containing derivatives. In the case of Sn(II) derivative, the potential of bis‐sulfoxide 2 as a pincer type ligand was suggested.

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