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Up- and downconversion emission studies in Er3+/Yb3+: Ca3 (PO4)2 phosphor for thermometry
Sensors and Actuators A: Physical ( IF 4.1 ) Pub Date : 2020-09-11 , DOI: 10.1016/j.sna.2020.112302
K.M. Krishna , S.P. Tiwari , A. Kumar , K. Kumar

Up- and downconversion emission and sensing sensitivity is studied in Er3+/Yb3+ co-doped biocompatible Ca3(PO4)2 phosphor synthesized via co-precipitation (CPT) and hydrothermal (HYDT) methods. The emission bands are observed at 523, 549 & 656 nm due to the 2H11/24I15/2, 4S3/24I15/2, and 4F9/24I15/2 transitions, respectively on excitation under 980 nm diode laser. The sample prepared via hydrothermal method has shown higher upconversion emission as compared to the sample prepared via co-precipitation method. The temperature sensing performance on green upconverted-emission from two thermally coupled 2H11/2 and 4S3/2 levels of Er3+ ion was measured in the 300–473 K temperature range and maximum sensor sensitivity of 0.34 %/K for HYDT and 0.26 %/K for CPT sample at 300 K is observed. Cell survivability at various sample concentrations (0 μM to 100 μM) was studied and finally, no significant toxicity on WI-38 cells was assessed by the MTT assay method.



中文翻译:

Er 3+ / Yb 3+:Ca 3(PO 4)2荧光粉的上转换和下转换发射光谱法用于测温

研究了通过共沉淀(CPT)和水热法(HYDT)合成的Er 3+ / Yb 3+共掺杂生物相容Ca 3(PO 42荧光粉的上下转换发射和传感灵敏度。发射带在523,549和656nm处观察到归因于2 ħ 11/2415/24小号3/2415/2,4 ˚F 9/2415 / 2分别在980 nm二极管激光器的激发下发生跃迁。与通过共沉淀法制备的样品相比,通过水热法制备的样品显示出更高的上转换发射。在300–473 K的温度范围内测量了两个热耦合的2 H 11/24 S 3/2能级的Er 3+离子在绿色上转换发射时的温度感测性能,最大传感器灵敏度为0.34%/ K在300 K下观察到CPT样品的HYDT和0.26%/ K。研究了在各种样品浓度(0μM至100μM)下的细胞存活率,最后,MTT分析方法未评估对WI-38细胞的明显毒性。

更新日期:2020-09-11
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