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Deposition and characterization of tungsten oxide (WO3) nanoparticles incorporated diamond-like carbon coatings using pulsed-DC PECVD
Materials Letters ( IF 2.7 ) Pub Date : 2020-09-11 , DOI: 10.1016/j.matlet.2020.128645
Funsho Olaitan Kolawole , Luis Bernardo Varela , Shola Kolade Kolawole , Marco Antonio Ramirez , André Paulo Tschiptschin

In this study a novel approach using pulsed-DC plasma enhanced chemical vapour deposition (DC-PECVD) to incorporate tungsten oxide nanoparticles into diamond-like carbon coatings (DLC) thin film deposited on tappet valve (metallic substrate) was successfully achieved. The DLC-W film obtained by incorporating WO3 nanoparticles into DLC was characterized using scanning electron microscope/energy dispersive spectroscopy (SEM/EDS), X-ray diffraction (XRD), Raman spectroscopy, scratch test, Rockwell C indention test and nano-hardness measurement. The thickness, hardness and elastic modulus were measured as 789.11 ± 16 nm, 18.64 ± 0.11 GPa and 152.03 ± 2.1 GPa respectively. The ID/IG was 0.95, D and G peaks positioned at 1341.66 and 1562.17 cm−1 respectively and W2C was observed from the XRD. The coating had a low apparent COF of 0.075 and excellent adhesion properties.



中文翻译:

使用脉冲直流PECVD沉积和表征掺入类金刚石碳涂层的氧化钨(WO 3)纳米颗粒

在这项研究中,成功​​实现了使用脉冲直流等离子体增强化学气相沉积(DC-PECVD)的新方法,将氧化钨纳米颗粒掺入沉积在挺杆阀(金属基底)上的类金刚石碳涂层(DLC)薄膜中。通过使用扫描电子显微镜/能量色散光谱(SEM / EDS),X射线衍射(XRD),拉曼光谱,划痕测试,罗克韦尔C压痕测试和纳米级扫描电镜对通过将WO 3纳米粒子掺入DLC所获得的DLC-W膜进行表征。硬度测量。测得的厚度,硬度和弹性模量分别为789.11±16 nm,18.64±0.11 GPa和152.03±2.1 GPa。I D / I G为0.95,D和G峰位于1341.66和1562.17 cm -1分别和W 2 C来自所述XRD进行了观察。该涂层具有0.075的低表观COF和优异的粘合性能。

更新日期:2020-09-20
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