当前位置: X-MOL 学术J. Eur. Ceram. Soc. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Triggering the aqueous interparticle association of γ‒Al2O3 hierarchical assemblies using divalent cations and cellulose nanofibers
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-09-11 , DOI: 10.1016/j.jeurceramsoc.2020.09.014
H. Hudelja , B. Wicklein , D. Kuščer , A. Kocjan

Understanding aqueous dispersion, rheological properties and colloidal stabilisation mechanisms of hierarchically assembled ceramic powders is important for progress in the fields of catalysis, separation and/or adsorption. The present study was designed to evaluate the rheological and sedimentation behaviour of highly loaded aqueous suspensions (up to φA = 0.126) containing AlN-powder-hydrolysis-derived, micron-sized, mesoporous, gamma alumina (MA) particulates with a high surface area (∼180 m2/g) dispersed with sodium polyacrylate (NaPAA). The as-prepared suspensions were prone to sedimentation and segregation. However, when divalent cations (Mg2+, Ca2+) or cellulose nanofibers were added, the formation of interparticle association networks in the aqueous suspensions containing MA particles was triggered, facilitating their long-term resistance to sedimentation lasting more than 12 weeks.



中文翻译:

使用二价阳离子和纤维素纳米纤维触发γ‒Al 2 O 3分层组装体的水颗粒间缔合

了解分层组装的陶瓷粉末的水分散性,流变性质和胶体稳定机理对于催化,分离和/或吸附领域的进展很重要。本研究的目的是高负荷的水性悬浮液的流变学和沉降行为评估(高达φ= 0.126)含有AlN粉末水解衍生的,微米尺寸的中孔,γ-氧化铝(MA)的颗粒具有高表面面积(约180 m 2 / g)分散有聚丙烯酸钠(NaPAA)。所制备的悬浮液易于沉淀和离析。但是,当二价阳离子(Mg 2 +,Ca 2+)或添加纤维素纳米纤维,引发了在包含MA颗粒的水悬浮液中形成颗粒间缔合网络,促进了其对沉淀的长期抵抗力超过12周。

更新日期:2020-10-30
down
wechat
bug