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Study on the effect of operating parameters towards CO2 absorption behavior of choline chloride – Monoethanolamine deep eutectic solvent and its aqueous solutions
Chemical Engineering and Processing: Process Intensification ( IF 3.8 ) Pub Date : 2020-09-11 , DOI: 10.1016/j.cep.2020.108142
Haryo Wibowo , Wenjuan Liao , Xuanyou Zhou , Caimeng Yu , Dicka Ar Rahim , Dwi Hantoko , Huan Qun , Mi Yan

In this study, the effect of absorption pressure and temperature towards the CO2 absorption capacity and rate of choline chloride - monoethanol amine deep eutectic solvent (ChCl-MEA DES) was evaluated. Water mixing into ChCl-MEA DES was also examined as a method to improve CO2 absorption behavior. Equilibrium experiments were done in a batch reactor and the data was analyzed using response surface methodology (RSM). Results suggested that the dominant mode of CO2 absorption by ChCl-MEA DES was physical absorption. The maximum capacity of CO2 absorption obtained in this study was 0.379 mol-CO2/mol-DES from absorption at (10 bar, 40 °C) using DES with 50 %v water. Water mixing up to 50 %v was found to nearly double the CO2 absorption capacity of ChCl-MEA DES compared to neat DES. Study into CO2 absorption rate by ChCl-MEA DES found that it is mainly influenced positively by pressure and water content, while not significantly influenced by temperature. CO2 absorption rate of ChCl-MEA DES with 50 %v water was found to be on average twice of that of neat DES. It was also found that water content up to 50 %v does not change the mechanism of CO2 absorption by ChCl-MEA DES.



中文翻译:

操作参数对胆碱氯化物-单乙醇胺深共熔溶剂及其水溶液对CO 2吸收行为的影响研究

在这项研究中,评估了吸收压力和温度对CO 2吸收容量和胆碱氯化物-单乙醇胺深共熔溶剂(ChCl-MEA DES)速率的影响。还检查了将水混入ChCl-MEA DES中作为改善CO 2吸收行为的方法。在间歇反应器中进行平衡实验,并使用响应面方法(RSM)分析数据。结果表明,ChCl-MEA DES吸收CO 2的主要方式是物理吸收。这项研究中获得的最大CO 2吸收容量为0.379 mol-CO 2/ mol-DES,使用DES与50%v的水在(10 bar,40°C)下吸收。发现与纯DES相比,混合至50%v的水几乎使ChCl-MEA DES的CO 2吸收能力提高一倍。通过ChCl-MEA DES对CO 2吸收率的研究发现,它主要受压力和水含量的正影响,而不受温度的显着影响。发现50%v的水对ChCl-MEA DES的CO 2吸收率平均是纯DES的两倍。还发现含水量高达50%v不会改变ChCl-MEA DES吸收CO 2的机理。

更新日期:2020-09-16
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