F⁻ ion conducting 60ZrF₄·30BaF₂·LaF₃·2AlF₃·7CsF (mol%) with outer mol% of xIn₂O₃ (x = 0, 5, 10) glasses were prepared using a conventional melting method, and structure and glass transition behavior were investigated using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and Raman spectroscopy. Impedance measurement reveals the glass with x = 10 shows F⁻ ion conductivity of 5 × 10⁻⁶ S/cm at 200 °C. F⁻ ion emission measurement was carried out for the first time using a sharpened glass tip, and the emission current was observed above the acceleration voltage of 2.5 kV at 200 °C and 1 × 10⁻⁴ Pa. After the F⁻ emission measurement, fluorine was detected on a Cu target substrate by using an energy-dispersive X-ray spectrometer. However, a small amount of glass component was also detected on the target substrate, suggesting the glass tip may also decompose. A good linear correlation is obtained between log(current) and the square root of the voltage, suggesting the emission current of F⁻ ion from the tip of glass is expressed by Schottky model.

˚F ^-离子传导60ZrF ₄ ·30BaF ₂ ·的LaF ₃ ·2AlF ₃与外摩尔％·7CsF（摩尔％）X在₂ ø ₃（X  = 0，5，10）使用常规的熔融法来制备玻璃，和使用X射线衍射（XRD），差示扫描量热法（DSC）和拉曼光谱研究了结构和玻璃化转变行为。阻抗测量揭示了与玻璃X  = 10描绘了f ^-的5×10离子电导率^-6  S / cm的在200℃下。˚F ^-离子发射测量使用锋利的玻璃尖端进行首次和2.5千伏的加速电压以上，观察到在200℃下发射电流和1×10 ^-4 帕在F后。^-发射测量，氟是通过使用能量色散X射线光谱仪在Cu靶基板上进行检测。但是，在目标基板上也检测到少量的玻璃成分，表明玻璃尖端也可能分解。是log（电流）和电压的平方根之间获得线性相关性良好的，这表明F的发射电流^-离子从玻璃的尖端通过肖特基模型表示。