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Physical properties of the layered oxypnictide Sr2ScFeAsO3: A Mossbauer study down to 1.7 K.
Journal of Physics: Condensed Matter ( IF 2.7 ) Pub Date : 2020-09-10 , DOI: 10.1088/1361-648x/abaeae
R Idczak , Z Bukowski , T T H Nguyen , V H Tran

A polycrystalline sample of Sr2ScFeAsO3 was studied by 57Fe Mössbauer spectroscopy down to 1.7 K. In contrast to the earlier Mössbauer data, the obtained in this work results indicate that Sr2ScFeAsO3 is in paramagnetic state down to 10 K, while the spectra recorded at 4.6 K and 1.7 K show a weak magnetic order of Fe moments in the Fe2As2 layers. Temperature dependences of isomer shift and quadrupole splitting/shift are compared with specific heat and electrical resistivity data from earlier investigations revealing different local Debye temperatures for the Fe2As2 and perovskite-related Sr2ScO3 layers. Finally, a fast decrease of the carrier density was observed below 80 K and this effect seems to be responsible for the absence of superconductivity in the studied compound.

中文翻译:

层状氧化锌 Sr2ScFeAsO3 的物理特性:Mossbauer 研究低至 1.7 K。

Sr2ScFeAsO3 的多晶样品通过低至 1.7 K 的 57Fe 穆斯堡尔光谱进行了研究。 与早期的穆斯堡尔数据相比,这项工作中获得的结果表明 Sr2ScFeAsO3 处于低至 10 K 的顺磁状态,而光谱记录在 4.6 K 和1.7 K 显示 Fe2As2 层中 Fe 矩的弱磁序。将异构体位移和四极分裂/位移的温度依赖性与早期研究的比热和电阻率数据进行比较,揭示 Fe2As2 和钙钛矿相关 Sr2ScO3 层的不同局部德拜温度。最后,在 80 K 以下观察到载流子密度的快速下降,这种效应似乎是研究化合物中不存在超导性的原因。
更新日期:2020-09-10
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