Optik Pub Date : 2020-09-10 , DOI: 10.1016/j.ijleo.2020.165574 Shuang Wang , Ya-jie Han , Lei Shi , Wei-yuan Zhang , Pan-mei Shi , Zhong-fei Mu , Si-Bo Shen , Xu-Lin Lu , Zhi-wei Zhang , Ai-jun Song
A series of red-emitting LaOF:xEu3+ (x = 0.03, 0.05, 0.07, 0.11, 0.13, 0.15 and 0.17) phosphors were successfully fabricated via precipitation reaction and calcination. The samples were evaluated by X-ray powder diffraction (XRD), transmission electron microscope (TEM), photoluminescence excitation (PLE) and emission (PL) spectra. It is found that the samples can be excited by near-ultraviolet (NUV) and blue light contributing to apply in phosphor-converted white light emitting diodes (WLEDs). The intense PL peaks were centered at 614 nm due to the 5D0 → 7F2 transition. Moreover, the PL intensity of sample modified with tetraethyl orthosilicate (TEOS) has been enhanced than that of La0.89OF:0.11Eu3+. Finally, the International Commission on Illumination (CIE) chromaticity of phosphors are located in red region. The correlated color temperature (CCT =2530 K) for La0.89OF:0.11Eu3+ modified with the concentration of 7 mol% of TEOS is in the range of “warm appearance”. The results showed that the phosphors are considered as the potential luminescence materials for warm light emitting diodes.
中文翻译:
原硅酸四乙酯修饰的发射LaOF:Eu 3+的红色荧光粉,可增强LED的发光强度
通过沉淀反应和煅烧成功地制备了一系列发红光的LaOF:x Eu 3+(x = 0.03、0.05、0.07、0.11、0.13、0.15和0.17)荧光粉。通过X射线粉末衍射(XRD),透射电子显微镜(TEM),光致发光激发(PLE)和发射(PL)光谱评估样品。发现样品可以被近紫外光(NUV)和蓝光激发,从而有助于应用于荧光粉转换白光发光二极管(WLED)。由于5 D 0 → 7 F 2,强烈的PL峰集中在614 nm处过渡。此外,用原硅酸四乙酯(TEOS)改性的样品的PL强度比La 0.89 OF:0.11Eu 3+增强。最后,国际照明委员会(CIE)荧光粉的色度位于红色区域。经浓度为7摩尔%的TEOS修饰的La 0.89 OF:0.11Eu 3+的相关色温(CCT = 2530 K)在“暖外观”范围内。结果表明,磷光体被认为是温暖发光二极管的潜在发光材料。