Palladium-catalyzed selective defluorinative sulfenylation for the synthesis of fluorovinylthioethers,Organic Chemistry Frontiers

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Palladium-catalyzed selective defluorinative sulfenylation for the synthesis of fluorovinylthioethers
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2020-09-09 , DOI: 10.1039/d0qo00818d
Shi-Yu He _{1,

2,

3,

4} , Xing-Guo Zhang _{1,

2,

3,

4,

5}

Affiliation

An efficient transformation of trifluoromethylated compounds to monofluoroalkenes was developed through Pd-catalyzed selective defluorinative sulfenylation. A variety of α-fluorovinylthioethers were prepared in good yields from α-trifluoromethylated benzyl bromides and odorless disulfides.

中文翻译：