Studies towards Pyridine‐Based N,N,O‐Gold(III) Complexes: Synthesis, Characterization and Application,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Studies towards Pyridine‐Based N,N,O‐Gold(III) Complexes: Synthesis, Characterization and Application
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-09-09 , DOI: 10.1002/ejoc.202001138
Thomas Nordbø Solvi ₁ , Ann Christin Reiersølmoen ₁ , Andreas Orthaber ₂ , Anne Fiksdahl ₁

Affiliation

Studies on gold(III) coordination of a series of new chiral polydentate (X,)N,O‐pyridine based ligands are reported. Successful coordination afforded novel chiral N,N,O‐tridentate Au(III) complexes with the 2‐pyridyl‐6‐[(1S,2S,5R)‐neomenthol‐1‐yl]pyridine ligand (¹H, ¹³C, ¹⁵N NMR, HRMS, IR, XRD). The chiral 2‐aryl‐6‐alkylpyridine alcohol ligands were prepared from 2,6‐dibromopyridine, (–)‐menthone or (+)‐camphor, and arylboronic acids. The new N,N,O‐ligated gold(III) complex was highly catalytic active and outperformed AuCl₃ in a cyclopropanation test reaction.

中文翻译：

吡啶基N，N，O-金（III）配合物的研究：合成，表征和应用

报道了一系列新型手性多齿（X，）N，O-吡啶基配体的金（III）配位研究。成功的配位提供了新型手性N，N，O-三齿Au（III）配合物与2-吡啶基-6-[（1 S，2 S，5 R）-新薄荷醇-1-基]吡啶配体（¹ H，¹³ C，¹⁵ N NMR，HRMS，IR，XRD）。手性2-芳基-6-烷基吡啶醇配体是由2,6-二溴吡啶，（-）薄荷酮或（+）樟脑和芳基硼酸制备的。新的N，N，O连接的金（III）络合物具有高催化活性，在环丙烷化测试反应中的性能优于AuCl ₃。

更新日期：2020-09-09

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11