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Effect of cerium oxide doping on the photocatalytic properties of rutile TiO2 films prepared by spray pyrolysis
Physica B: Condensed Matter ( IF 2.8 ) Pub Date : 2020-09-08 , DOI: 10.1016/j.physb.2020.412544
Nenad Radić , Boško Grbić , Srdjan Petrović , Stevan Stojadinović , Nenad Tadić , Plamen Stefanov

The spray pyrolysis is fast and simple method for deposition of CeO2 – rutile TiO2 coatings on stainless steel substrate. The coatings were deposited on stainless steel substrate and characterized by XRD, AFM, XPS, Raman, DRS and photoactivity test for methyl orange decolorization. Photoactivity of CeO2 – rutile TiO2 coatings increase with increasing CeO2 content up to 5 wt% and further increase of CeO2 content leads to decrease of photoactivity. Improvements of photoactivity originate from close contact between CeO2 and rutile TiO2 particles which create numerous centers able to produce very reactive radical species. Besides, the close contact between the CeO2 and rutile TiO2 provides easier charge transfer facilitating the formation of electron/hole pairs that is a necessary step in the overall photocatalytic process.



中文翻译:

氧化铈掺杂对喷雾热解金红石型TiO 2薄膜光催化性能的影响

喷雾热解是在不锈钢基材上沉积CeO 2-金红石型TiO 2涂层的快速简便的方法。将涂层沉积在不锈钢基材上,并通过XRD,AFM,XPS,拉曼,DRS和光活性测试对甲基橙进行脱色。CeO 2-金红石型TiO 2涂层的光活性随CeO 2含量增加至5 wt%而增加,而CeO 2含量的进一步增加导致光活性降低。CeO 2和金红石TiO 2紧密接触可提高光活性产生许多中心的粒子,这些中心能够产生非常活泼的自由基。此外,CeO 2和金红石TiO 2之间的紧密接触提供了更容易的电荷转移,促进了电子/空穴对的形成,这是整个光催化过程中的必要步骤。

更新日期:2020-09-09
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