ADMET polymers: synthesis, structure elucidation, and function,Materials Chemistry Frontiers

当前位置： X-MOL 学术 › Mater. Chem. Front. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

ADMET polymers: synthesis, structure elucidation, and function
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2020-09-07 , DOI: 10.1039/d0qm00273a
Julia Pribyl _{1,

2,

3,

4,

5} , Kenneth B. Wagener _{1,

2,

3,

4,

5} , Giovanni Rojas _{1,

2,

3,

4,

5}

Affiliation

Acyclic Diene Metathesis polycondensation produces materials with well-defined primary structures, perfection that is the consequence of symmetry imparted by monomer design. Diverse functionalities can be incorporated either in the polymer backbone or as pendant groups; chemical compatibility of the functional group with the catalyst is a requirement. Structural perfection led to structure/property investigations that would be difficult in imprecise systems. This comprehensive review summarizes the synthetic strategies for production of ADMET polymers. Further presented are the effects on secondary structure of controlling branch identity, in-chain functional groups, and frequency along the polymer chain. Results of spectroscopic, thermal and imaging techniques have been key for understanding the relationships between structure and properties.

中文翻译：

ADMET聚合物：合成，结构阐明和功能

无环二烯复分解缩聚反应产生的材料具有定义明确的一级结构，这是单体设计赋予对称性的结果。可以将各种官能团结合到聚合物主链中或作为侧基。官能团与催化剂的化学相容性是必需的。结构上的完善导致结构/属性研究在不精确的系统中很难进行。这份全面的综述总结了ADMET聚合物生产的合成策略。进一步介绍了控制支链身份，链内官能团和沿聚合物链频率对二级结构的影响。光谱，热学和成像技术的结果对于理解结构与性能之间的关系至关重要。

更新日期：2020-11-03

点击分享查看原文

点击收藏

阅读更多本刊最新论文