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Rate coefficients for the reactions of OH with butanols from 298 K to temperatures relevant for low‐temperature combustion
International Journal of Chemical Kinetics ( IF 1.5 ) Pub Date : 2020-09-07 , DOI: 10.1002/kin.21422
Samantha L. Sime 1 , Mark A. Blitz 1, 2 , Paul W. Seakins 1
Affiliation  

Rate coefficients for the reactions of OH with n, s, and iso‐butanol have been measured over the temperature range 298 to ∼650 K. The rate coefficients display significant curvature over this temperature range and bridge the gap between previous low‐temperature measurements with a negative temperature dependence and higher temperature shock tube measurements that have a positive temperature dependence. In combination with literature data, the following parameterizations are recommended:

中文翻译:

OH与丁醇从298 K到与低温燃烧有关的温度的反应速率系数

已在298至650 K的温度范围内测量了OH与n,s和异丁醇反应的速率系数。速率系数在该温度范围内显示出明显的曲率,并弥合了先前的低温测量与负温度依赖性和较高温度的冲击管测量值具有正温度依赖性。结合文献数据,建议进行以下参数化:
更新日期:2020-10-30
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