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Effect of Ti on microstructure, mechanical properties and corrosion resistance of Zr-Ta-Ti alloys processed by spark plasma sintering
Journal of Central South University ( IF 3.7 ) Pub Date : 2020-09-07 , DOI: 10.1007/s11771-020-4440-9
Guo-lin Xue , Hai-lin Yang , Hai-xia Xing , Chuan-ren Ye , Jue Liu , Jing-lei Miao , Jian-ming Ruan

The microstructure, mechanical properties and corrosion resistance of Zr-30%Ta and Zr-25%Ta-5%Ti alloy prepared by spark plasma sintering (SPS) technology were investigated. The experimental results showed that the Zr-Ta-Ti alloys made by the SPS processing have a low level of porosity with the relative density of 96%–98%. The analyses of XRD and TEM revealed that the Zr-30Ta alloy consists of α+β phase, and the Zr-25Ta-5Ti alloy belongs to the near β type alloy containing a small amount of α and ω phases. With the addition of Ti, the elastic modulus of the alloys was decreased from (99.5±7.2) GPa for Zr-30Ta alloy to (73.6±6.3) GPa for Zr-25Ta-5Ti alloy. Furthermore, it is shown that, in comparison to CP-Ti and Ti-6Al-4V alloy, the Zr-Ta-Ti alloy produced in this work offers an improved corrosion resistance due to the more stable ZrO2 and Ta2O5 generated in the passivation film on the surface of the alloys. This study demonstrates that Zr-Ta-Ti alloys are a promising candidate of novel metallic biomaterials.



中文翻译:

Ti对火花等离子体烧结Zr-Ta-Ti合金显微组织,力学性能和耐蚀性的影响

研究了通过火花等离子体烧结(SPS)技术制备的Zr-30%Ta和Zr-25%Ta-5%Ti合金的组织,力学性能和耐蚀性。实验结果表明,通过SPS加工制成的Zr-Ta-Ti合金的孔隙率较低,相对密度为96%–98%。XRD和TEM分析表明,Zr-30Ta合金由α+β相组成,Zr-25Ta-5Ti合金属于含有少量αω的近β型合金。阶段。随着Ti的添加,合金的弹性模量从Zr-30Ta合金的(99.5±7.2)GPa降低到Zr-25Ta-5Ti合金的(73.6±6.3)GPa。此外,示出的是,相比于CP-Ti系和Ti-6Al-4V合金,在这项工作报价产生的改进的耐腐蚀性的Zr-TA-Ti合金由于更稳定的ZrO 2和Ta 2 ö 5产生在合金表面的钝化膜中。这项研究表明Zr-Ta-Ti合金是新型金属生物材料的有希望的候选者。

更新日期:2020-09-08
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