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Selective hydrogenation of oxalic acid to glycolic acid and ethylene glycol with a ruthenium catalyst
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.7 ) Pub Date : 2020-09-05 , DOI: 10.1007/s11144-020-01843-3
Jackson H. S. Santos , Jadiete T. S. Gomes , Mohand Benachour , Eliane B. M. Medeiros , Cesar A. M. Abreu , Nelson M. Lima-Filho

The hydrogenation of the oxalic acid was evaluated with a ruthenium micro-mesoporous catalyst (5 wt%/activated carbon, 710 m2 g−1, 0.39 cm3 g−1), at 120 °C–150 °C under 80.0 bar in a slurry reactor, for the development of glycolic acid and ethylene glycol productions. The kinetic behavior of the process based on a surface mechanism was established according to the Langmuir–Hinshelwood approach. The mass balance equations fitted to the experimental data provided orders of magnitude for the specific reaction rates, reaching 1.93 × 10–1 h−1 for the hydrogenation of oxalic acid into glycolic acid at 130 °C and 2.51 × 10–2 h−1 for the production of volatile products at 150 °C. The kinetic selectivities under these conditions, 130 °C and 150 °C, were circa 70% for the production of glycolic acid, while for the volatile compounds was reached 87%.



中文翻译:

用钌催化剂将草酸选择性加氢为乙醇酸和乙二醇

草酸的氢化与钌微-中孔催化剂(5%重量/活性炭,710米评价2 克-1,0.39厘米3 克-1中),在120℃-150℃下80.0巴淤浆反应器,用于开发乙醇酸和乙二醇产品。根据Langmuir-Hinshelwood方法,建立了基于表面机理的过程动力学行为。的质量平衡方程装配到用于特定的反应速率提供数量级的实验数据,达到1.93×10 -1  ħ -1为草酸的氢化成乙醇酸在130℃和2.51×10 -2  ħ -1用于在150°C下生产挥发性产品。在130°C和150°C的条件下,对于乙醇酸的生产,动力学选择性约为70%,而对于挥发性化合物,其动力学选择性达到87%。

更新日期:2020-09-06
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