当前位置: X-MOL 学术Mater. Res. Express › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Quantifying the influence of calcium ion concentration on the corrosion of high-purity magnesium, AZ91, WE43 in modified Hanks’ solutions
Materials Research Express ( IF 1.8 ) Pub Date : 2020-09-03 , DOI: 10.1088/2053-1591/abb1f4
Baptiste Py 1, 2 , Sean Johnston 1 , Alexander Hardy 1 , Zhiming Shi 1 , Krzysztof Wolski 2 , Andrej Atrens 1
Affiliation  

The corrosion rate in a modified Hanks’ solution (containing no Ca 2+ ions) was higher than in Hanks’ solution. The increase was by a factor of ∼12 for HP Mg and AZ91, and a factor of ∼6 for WE43. This quantitatively highlights the critical role of Ca 2+ ions for Mg corrosion in synthetic body fluids. The Ca 2+ ion containing solutions produced a dense corrosion-product layer of hydroxyapatite, Ca 3 (PO 4 ) 2 ) · Ca(OH) 2 , a greater fraction of which stayed on the corroding surface (∼0.2–0.3) compared with the Ca 2+ ion free solutions which produced magnesium phosphate, Mg 3 (PO 4 ) 2 .

中文翻译:

量化钙离子浓度对改良汉克斯溶液中高纯度镁,AZ91,WE43腐蚀的影响

改良的汉克斯溶液(不含Ca 2+离子)的腐蚀速率高于汉克斯溶液。HP Mg和AZ91的增加量约为12,WE43的增加量约为6。这定量地突出了Ca 2+离子对于合成体液中Mg腐蚀的关键作用。含Ca 2+的溶液产生了密集的羟基磷灰石腐蚀产物层,即Ca 3(PO 4)2)·Ca(OH)2,与腐蚀表面相比,其中大部分保留在腐蚀表面上(〜0.2–0.3)。不含Ca 2+的离子溶液,产生磷酸镁Mg 3(PO 4)2。
更新日期:2020-09-05
down
wechat
bug