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Antimony-Assisted Assembly of Basic Supertetrahedral Clusters into Heterometallic Chalcogenide Supraclusters.
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-09-04 , DOI: 10.1021/acs.inorgchem.0c02097
Yayun Ding 1 , Jiaxu Zhang 1 , Chengdong Liu 1 , Xiao-Li Wang 1 , Zhou Wu 1 , Xiang Wang 1 , Rui Zhou 1 , Dong-Sheng Li 2 , Tao Wu 1
Affiliation  

Reported here are two new heterometallic chalcogenide supraclusters ([Ga56Sb16S136] and [In36Sb6S75]), which present new self-assembly modes of basic supertetraheral clusters with the assistance of antimony ions. This work demonstrates the crucial role of the added metal ions with nontetrahedral coordination geometry in developing supertetrahedral-cluster-based supraclusters with a new level of complexity.

中文翻译:

基本超四面体簇的锑辅助组装成异金属硫属元素化物超团簇。

这里报道了两种新的杂金属硫族化物超簇([Ga 56 Sb 16 S 136 ]和[In 36 Sb 6 S 75 ]),它们在锑离子的辅助下呈现了基本的超四面体簇的新自组装模式。这项工作证明了添加具有非四面体配位几何形状的金属离子在开发具有新高度复杂性的基于超四面体-簇的超簇中的关键作用。
更新日期:2020-09-21
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